A simple model for the evolution of disc galaxies: the Milky Way     

Thorsten Naab  Jeremiah P. Ostriker 《Monthly notices of the Royal Astronomical Society》2006,366(3):899-917

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Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates     

Philippe E. Raison  Regis Jardin  Daniel Bouëxière  Rudy J. M. Konings  Thorsten Geisler  Claudiu C. Pavel  Jean Rebizant  Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.  相似文献   

Equation of state of MgGeO3 perovskite to 65 GPa: comparison with the post-perovskite phase     

C. E. Runge  A. Kubo  B. Kiefer  Y. Meng  V. B. Prakapenka  G. Shen  R. J. Cava  T. S. Duffy 《Physics and Chemistry of Minerals》2006,33(10):699-709

The equation of state of MgGeO₃ perovskite was determined between 25 and 66 GPa using synchrotron X-ray diffraction with the laser-heated diamond anvil cell. The data were fit to a third-order Birch–Murnaghan equation of state and yielded a zero-pressure volume (V ₀) of 182.2 ± 0.3 Å³ and bulk modulus (K ₀) of 229 ± 3 GPa, with the pressure derivative (K′₀ = (?K ₀/?P) _T ) fixed at 3.7. Differential stresses were evaluated using lattice strain theory and found to be typically less than about 1.5 GPa. Theoretical calculations were also carried out using density functional theory from 0 to 205 GPa. The equation of state parameters from theory (V ₀ = 180.2 Å³, K ₀ = 221.3 GPa, and K′₀ = 3.90) are in agreement with experiment, although theoretically calculated volumes are systematically lower than experiment. The properties of the perovskite phase were compared to MgGeO₃ post-perovskite phase near the observed phase transition pressure (～65 GPa). Across the transition, the density increased by 2.0(0.7)%. This is in excellent agreement with the theoretically determined density change of 1.9%; however both values are larger than those for the (Mg,Fe)SiO₃ phase transition. The bulk sound velocity change across the transition is small and is likely to be negative [?0.5(1.6)% from experiment and ?1.2% from theory]. These results are similar to previous findings for the (Mg,Fe)SiO₃ system. A linearized Birch–Murnaghan equation of state fit to each axis yielded zero-pressure compressibilities of 0.0022, 0.0009, and 0.0016 GPa^?1 for the a, b, and c axis, respectively. Magnesium germanate appears to be a good analog system for studying the properties of the perovskite and post-perovskite phases in silicates.  相似文献   

On the effect of temperature and strain-rate dependent viscosity on global mantle flow, net rotation, and plate-driving forces     

Thorsten W. Becker 《Geophysical Journal International》2006,167(2):943-957

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Model identification for hydrological forecasting under uncertainty   总被引：2，自引：2，他引：2  

Thorsten Wagener  Hoshin V. Gupta 《Stochastic Environmental Research and Risk Assessment (SERRA)》2005,19(6):378-387

Methods for the identification of models for hydrological forecasting have to consider the specific nature of these models and the uncertainties present in the modeling process. Current approaches fail to fully incorporate these two aspects. In this paper we review the nature of hydrological models and the consequences of this nature for the task of model identification. We then continue to discuss the history (“The need for more POWER‘’), the current state (“Learning from other fields”) and the future (“Towards a general framework”) of model identification. The discussion closes with a list of desirable features for an identification framework under uncertainty and open research questions in need of answers before such a framework can be implemented.  相似文献   

Molecular formulae of marine and terrigenous dissolved organic matter detected by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry     

Boris P. Koch  Matthias Witt  Thorsten Dittmar 《Geochimica et cosmochimica acta》2005,69(13):3299-3308

The chemical structure of refractory marine dissolved organic matter (DOM) is still largely unknown. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS) was used to resolve the complex mixtures of DOM and provide valuable information on elemental compositions on a molecular scale. We characterized and compared DOM from two sharply contrasting aquatic environments, algal-derived DOM from the Weddell Sea (Antarctica) and terrigenous DOM from pore water of a tropical mangrove area in northern Brazil. Several thousand molecular formulas in the mass range of 300-600 Da were identified and reproduced in element ratio plots. On the basis of molecular elemental composition and double-bond equivalents (DBE) we calculated an average composition for marine DOM. O/C ratios in the marine samples were lower (0.36 ± 0.01) than in the mangrove pore-water sample (0.42). A small proportion of chemical formulas with higher molecular mass in the marine samples were characterized by very low O/C and H/C ratios probably reflecting amphiphilic properties. The average number of unsaturations in the marine samples was surprisingly high (DBE = 9.9; mangrove pore water: DBE = 9.4) most likely due to a significant contribution of carbonyl carbon. There was no significant difference in elemental composition between surface and deep-water DOM in the Weddell Sea. Although there were some molecules with unique marine elemental composition, there was a conspicuous degree of similarity between the terrigenous and algal-derived end members. Approximately one third of the molecular formulas were present in all marine as well as in the mangrove samples. We infer that different forms of microbial degradation ultimately lead to similar structural features that are intrinsically refractory, independent of the source of the organic matter and the environmental conditions where degradation took place.  相似文献   

Late Miocene to Early Pliocene blueschist from Taiwan and its exhumation via forearc extraction          下载免费PDF全文

Sascha Sandmann  Thorsten J. Nagel  Nikolaus Froitzheim  Kamil Ustaszewski  Carsten Münker 《地学学报》2015,27(4):285-291

Blueschist facies rocks in the Yuli Belt of Taiwan's Central Range record ongoing subduction of the Eurasian plate. We present a prograde Lu–Hf garnet–whole‐rock age of 5.1 ± 1.7 Ma from a retrogressed blueschist in the Yuli Belt. This age is considerably younger than the previously assumed age of 14–8 Ma for high‐pressure metamorphism in the Yuli Belt and represents the youngest Lu–Hf garnet age ever recorded for blueschist facies metamorphism. The age sheds new light on the palaeogeographic origin and exhumation scenario of the Yuli Belt. We propose that the Yuli Belt originated from the ocean–continent boundary of the Chinese passive margin. It was subducted eastward during collision with the Luzon island arc and rapidly exhumed when the forearc lithosphere was removed from above the continental slab by discrete subduction (extraction). This process reduces the pressure above the continental slab and may prompt the ascent of subducted crust into the opening gap. Thus, it can control the exhumation of high‐pressure rocks.  相似文献   

Unraveling complex hydrogeological processes in Andean basins in south‐central Chile: An integrated assessment to understand hydrological dissimilarity          下载免费PDF全文

Enrique Muñoz  José Luis Arumí  Thorsten Wagener  Ricardo Oyarzún  Victor Parra 《水文研究》2016,30(26):4934-4943

Groundwater storage, drainage, and interbasin water exchange are common hydrological processes but often difficult to quantify due to a lack of local observations. We present a study of three volcanic mountainous watersheds located in south‐central Chile (~36.9 ° S) in the Chillán volcanic complex (Chillán, Renegado, and Diguillín river basins). These are neighboring basins that are similar with respect to the metrics normally available for characterization everywhere (e.g., precipitation, temperature, and land cover). In a hydrological sense, similar (proportional) behavior would be expected if these catchments would be characterized with this general information. However, these watersheds show dissimilar behavior when analyzed in detail. The surface water balance does not fit for any of these watersheds individually; however, the water balance of the whole system can be explained by likely interbasin water exchanges. The Renegado river basin has an average annual runoff per unit of area on the order of 60–65% less than those of the Diguillín and Chillán rivers, which is contradictory to the hydrological similarity among the basins. To understand the main processes that control streamflow generation, two analyses were performed: (a) basin metrics (land cover, geologic, topographic, and climatological maps) and hydro‐meteorological data analyses and (b) a water balance model approach. The analyses contribute to a plausible explanation for the hydrogeological processes in the system. The soils, topography, and geology of the Chillán–Renegado–Diguillín system favor the infiltration and groundwater movements from the Renegado river basin, mainly to the neighboring Diguillín basin. The interbasin water exchanges affect hydrological similarity and explain the differences observed in the hydrological processes of these three apparently similar volcanic basins. The results highlight the complexity of hydrological processes in volcanic mountainous systems and suggest that a simple watershed classification approach based on widely available data is insufficient. Simple local analyses such as specific flow analysis with a review of the geology and morphology can contribute to a better understanding of the hydrology of volcanic mountainous areas.  相似文献   

Characterization of dissolved organic matter across the Subtropical Convergence off the South Island,New Zealand     

Michael Gonsior  Barrie M. Peake  William T. Cooper  David C. Podgorski  Juliana D'Andrilli  Thorsten Dittmar  William J. Cooper 《Marine Chemistry》2011,123(1-4):99-110

Dissolved organic matter (DOM) was investigated along a gradient across the Subtropical Convergence (STC) off the South Island, New Zealand. Ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS), excitation emission matrix fluorescence (EEM) spectroscopy, and molecular lignin analysis techniques were used to study this DOM. The analysis revealed a group of compounds found only in the coastal DOM samples, which were also characterized by an elevated terrestrial DOM fluorescence pattern and elevated lignin content if compared to the offshore samples. This group exhibited a high degree of carbon unsaturation, as evident from high double bond equivalence minus oxygen values (DBE-O > 9) and maximum fluorescence intensity. Sulfur-containing molecular formulae for summer DOM samples were much more abundant across the entire transect of the STC compared to winter and exhibited distinctly different hydrogen:carbon and oxygen:carbon elemental ratios, suggesting a possible correlation between biological activity and sulfur compounds. The molecular formulae common to all STC samples were compared with those calculated for DOM extracted from freshwater collected from a stream discharging into Doubtful Sound (West Coast, New Zealand). ESI-FT-ICR-MS measurements undertaken in negative electrospray ionization (ESI?) mode indicated that 30% of the molecular formulae were present in both types of DOM, while in positive ESI mode (ESI+) over 90% of the formulae were present in all samples. Hence, a significant portion of the molecular formulae assigned to the solid-phase extractable DOM pool (SPE-DOM) appear to be identical in oceanic and freshwater samples.  相似文献   

Comparison of lightning activity and radar-retrieved microphysical properties in EULINOX storms     

Thorsten Fehr  Nikolai Dotzek  Hartmut Hller 《Atmospheric Research》2005,76(1-4):167

A combined analysis of microphysical thunderstorm properties derived by C-band polarimetric Doppler radar measurements and lightning observations from two ground-based systems are presented. Three types of storms, a multicell, a supercell, and a squall line, that were observed during the European Lightning Nitrogen Oxides project (EULINOX) are investigated. Correlations are sought between the mass of rain, graupel, hail, and snow derived form radar observations at different height levels and the electrical activity, represented either by cloud-to-ground or intracloud flashes. These relationships are explained by connecting the radar-derived properties with the non-inductive charging process. For the multicell and the supercell storm, the lightning activity can be linearly correlated to both the hydrometeor total mass and class specific mass in the upper part of the storm. It is shown that the fractions of graupel and hail above the −20 °C-level in these storms positively correlate with the intracloud flash activity in the supercell, and negatively for the cloud-to-ground lightning frequency in the multicell. No such relation can be established for the squall line, indicating that the convective organization plays a crucial role in the lightning development. The analysis of the masses in the different storms shows that lightning activity cannot be parameterized by total mass alone, other parameters have to be identified. The results provide important information for all lightning studies that rely on bulk properties of thunderstorms, e.g., the parameterization of lightning in mesoscale models or the nowcasting of lightning by radar.  相似文献